Weighted average atomic mass (IUPAC 2021) from isotope masses and natural abundances. Supports all elements 1–92, atomic weight intervals (boron, lithium...), real‑time pie chart.
| Isotope label | Mass (amu) | Natural abundance (%) | Contribution (amu) | |
|---|---|---|---|---|
| 11.871600 | ||||
| 0.139136 |
Isotopic abundance (%)
The atomic mass (also called relative atomic mass, symbol Ar) of an element is the weighted average mass of its stable isotopes, taking into account their natural abundances. Unlike mass number, atomic mass is not an integer because it reflects isotopic mixtures. This value is fundamental to stoichiometry, mass spectrometry, and understanding periodic trends.
Where fractional abundance = (percent abundance) / 100. For example, Chlorine-35 (34.9689 amu, 75.77%) and Chlorine-37 (36.9659 amu, 24.23%) give Ar ≈ 35.45 amu.
Modern atomic weights are determined using high‑precision mass spectrometers (e.g., TIMS, MC‑ICP‑MS). The IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW) evaluates and publishes standard atomic weights every two years. Our calculator uses reference data from NIST and IUPAC Technical Reports. For elements like carbon, the standard atomic weight is 12.011 ± 0.001 due to 13C natural variations.
In chemical reactions, atoms combine in mass ratios determined by atomic masses. Without accurate weighted averages, molar mass calculations for compounds like CO2 or H2O would be inconsistent. The concept also underpins isotope dilution analysis and radiometric dating. The tool’s dynamic table allows you to experiment with hypothetical isotope compositions — essential for teaching isotope fractionation and nuclear chemistry.
Isotopes of Chlorine: 35Cl (34.968852 amu, 75.76%) and 37Cl (36.965903 amu, 24.24%). Weighted average = (34.968852×0.7576) + (36.965903×0.2424) = 35.453 amu. The IUPAC standard atomic weight of chlorine is 35.45 ± 0.01. The slight variation in natural samples (e.g., marine vs. terrestrial) leads to the uncertainty. Our calculator reproduces this with high accuracy, demonstrating the power of isotopic weighting.